? 恭喜黄龙同学在Journal of Alloys and Compounds发表学术论文

祝贺黄龙同学在Applied Surface Science发表学术论文 ?

July 25, 2017

祝贺朱小磊同学在Electrochimica Acta发表学术论文

祝贺朱小磊同学在Electrochimica Acta发表学术论文:

Alkaline intercalation of Ti3C2 MXene for simultaneous electrochemical detection of Cd(II), Pb(II), Cu(II) and Hg(II), Xiaolei Zhu#, Bingchuan Liu#, Huijie Hou, Zhenying Huang, Kemal Mohammed Zeinu, Long Huang, Xiqing

Yuan, Dabin Guo, Jingping Hu*, Jiakuan Yang*, Electrochimica Acta, 248 (2017), 46–57(全文:http://dx.doi.org/10.1016/j.electacta.2017.07.084 (http://dx NULL.doi NULL.org/10 NULL.1016/j NULL.electacta NULL.2017 NULL.07 NULL.084)

Highlights

? Two-dimensional hydroxyl terminated alk-Ti3C2 was prepared by selective chemical etching and KOH intercalation.
? The surface chemistry of Ti3C2 has significant influence on its sensing performance.
? Mutual interference among Cd(II), Pb(II), Cu(II) and Hg(II) was discussed.
? The alk-Ti3C2 modified GCE exhibited excellent performance toward simultaneous detection of Cd(II), Pb(II), Cu(II) and Hg(II).

论文摘要Abstract

Two-dimensional accordion-like alk-Ti3C2 was prepared by acid etching and alkaline intercalation treatment, and demonstrated as a new platform for the simultaneous electrochemical detection toward multiple heavy metal ions using square wave anodic stripping voltammetry. The alk-Ti3C2 modified electrode exhibited significantly improved electrochemical response in comparison with the Ti3C2 modified electrode due to the unique morphology and surface chemistry characteristics. Key operational parameters including pH, deposition potential and deposition time were optimized for the determination of trace heavy metal ions. Under the optimum conditions, it exhibited a high sensitivity superior to most of reported values and good linear correlations, with a detection limit of 0.098 μM, 0.041 μM, 0.032 μM and 0.130 μM for Cd(II), Pb(II), Cu(II) and Hg(II), respectively. Furthermore, mutual interference among the four target metal ions was explored, and the preferential deposition of Pb(II) in the presence of other three metal ions together with an enhanced Hg(II) sensitivity in the presence of Cd(II) were discovered. This method offers a new strategy for heavy metal detection using MXenes materials.