? 祝贺徐继坤博士在Bioresource Technology发表学术论文

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March 10, 2017

祝贺袁喜庆同学在Chemical Engineering Journal发表学术论文

祝贺袁喜庆同学在Chemical Engineering Journal发表学术论文:

Separator modified with N,S co-doped mesoporous carbon using egg shell as template for high performance lithium-sulfur batteries, Xiqing Yuan, Longsheng Wu, Xiulin He, Kemal Zeinu, Long Huang, Xiaolei Zhu, Huijie Hou, Bingchuan Liu, Jingping Hu*, Jiakuan Yang*, Chemical Engineering Journal, 2017 (已接受,全文:http://dx.doi.org/10.1016/j.cej.2017.03.022 (http://dx NULL.doi NULL.org/10 NULL.1016/j NULL.cej NULL.2017 NULL.03 NULL.022)

Highlights

?? ? N,S co-doped hollow porous carbon synthesized by egg shell template method.
???? The discharge capacity of the second cycle retained at 1467 mAh g-1 at 1 C rate.
???? Pyridinic N and thiosulphate retard the dissolution and shuttling of polysulfides.

论文摘要 Abstract

The migration of long chain soluble lithium polysulfides through the separator to the anode, the so called “shuttle effect”, is one of the major issues responsible for the capacity degradation of lithium-sulfur (Li-S) batteries. In this work, N and S co-doped mesoporous carbon was prepared by a novel egg shell template method and utilized to modify the separator for high performance Li-S batteries. The discharge capacity of the second cycle retained at 1467 mAh g-1 at 1 C after 200 cycles and decayed at 0.20% per charge-discharge cycle, and a reversible capacity of 561 mAh g-1 was achieved even at 5 C rate after 200 cycles. The prepared material showed a porous hollow sphere morphology with larger surface area and N and S co-doped that can provide great electrochemical property as well as surface chemistry for the adsorption of the intermediate polysulfides. After separator modification, XPS analysis revealed that pyrrolic-type N, pyridinic-like N, and thiosulphate were the major factors contributing to the superior electrochemical performance of the CS/S cathode. This work also provided a rational design strategy for the modification of separator to effectively utilize the active sulfur and to retard the migration of dissolved polysulfides, which enhanced the performance of high energy density Li-S batteries with long cycling life.